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CH3COONa已知浓度、电离平衡常数求pH,水解度

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CH3COONa已知浓度、电离平衡常数求pH,水解度
CH3COONa浓度为0.1mol/L
CH3COOH电离平衡常数k为1.8*10^-5
求pH值,水解度
CH3COONa已知浓度、电离平衡常数求pH,水解度
设:水解平衡时的[OH-]为y (mol/L)
Ac- + H2O = HAc + OH-
平衡时:c-y y y
K = [HAc] × [OH-] ÷[Ac-]
= ([HAc] × [OH-] × [H+] )÷ ([Ac-] × [H+])
= Kw ÷ Ka
K= Kw ÷ Ka = 1.0*10^-14 ÷ 1.8*10^-5 = 5.56*10^-10
∵[HAc] × [OH-] ÷[Ac-] = y^2 / ( c-y) = K (∵ (c-y) ≈ c )
∴ y = √ ( c × K)
= √ (0.1*5.56*10^-10) = 7.45*10^-6 (mol/L)
POH= -Lg(7.45*10^-6)=5.13
因此:PH = 14 - 5.13 = 8.87
水解度=y ÷ c*100% = 7.45*10^-6 ÷0.1 × 100% = 0.00745%